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Which of the following electron configurations is not possible for an atom in an excited state?


A) 1s22s22p63s23p63d104s14p1
B) 1s22s22p63s13p5
C) 1s22s22p63s23p23d2
D) 1s22s22p63s23p63d104s2
E) 1s22s22p63s23p63d104s14p3

F) B) and C)
G) C) and E)

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Electron affinities become increasingly positive toward the right hand end of a period.

A) True
B) False

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Which one of the following equations correctly represents the process relating to the ionization energy of X?


A) X(s) → X+(g) + e-
B) X2(g) → X+(g) + X-(g)
C) X(g) + e- → X-(g)
D) X-(g) → X(g) + e-
E) X(g) → X+(g) + e-

F) C) and D)
G) A) and D)

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"Each electron in an atom must have its own unique set of quantum numbers" is a statement of


A) the aufbau principle.
B) the Pauli exclusion principle.
C) Hund's rule.
D) the periodic law.
E) Heisenberg's principle.

F) A) and B)
G) A) and C)

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Which of the following electron configurations is correct for the excited state of an element?


A) [He]2s22p5
B) [Ne]3s23p1
C) [Ar]4s14p1
D) [Kr]5s24d7
E) [He]1p1

F) B) and C)
G) A) and D)

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Energy states of atoms containing more than one electron arise from nucleus-electron and electron-electron interactions. Which of the following statements correctly describes these effects?


A) Larger nuclear charge lowers energy, more electrons in an orbital lowers energy.
B) Larger nuclear charge lowers energy, more electrons in an orbital increases energy.
C) Smaller nuclear charge lowers energy, more electrons in an orbital lowers energy.
D) Smaller nuclear charge lowers energy, more electrons in an orbital increases energy.
E) None of these choices are correct.

F) C) and E)
G) None of the above

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The most basic oxides are formed from elements found in the __________________ region of the periodic table.


A) upper right
B) upper left
C) center
D) lower right
E) lower left

F) C) and D)
G) A) and E)

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Which of the following atoms will be diamagnetic?


A) Cr
B) Ru
C) Fe
D) Pt
E) Cd

F) C) and D)
G) None of the above

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of potassium, K.


A) 4, 1, -1, ½
B) 4, 1, 0, ½
C) 4, 0, 1, ½
D) 4, 0, 0, ½
E) 4, 1, 1, ½

F) A) and D)
G) C) and D)

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Elements with the highest first ionization energies are found in the ___________ region of the periodic table.


A) lower left
B) upper left
C) center
D) lower right
E) upper right

F) B) and C)
G) A) and B)

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Select the correct set of quantum numbers (n, l, ml, ms) for the highest energy electron in the ground state of tin, Sn.


A) 5, 2, -1, ½
B) 5, 2, 0, ½
C) 5, 1, 2, ½
D) 5, 1, 0, ½
E) 5, 2, 1, ½

F) D) and E)
G) A) and E)

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How many valence electrons are there in an atom with the electron configuration [noble gas]ns2(n - 1) d8?


A) 2
B) 6
C) 8
D) 10
E) None of these choices are correct.

F) B) and E)
G) A) and E)

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What is the correct order of decreasing size of the following ions?


A) P3- > Cl- > K+ > Ca2+
B) Ca2+ > K+ > Cl- > P3-
C) K+ > Cl- > Ca2+ > P3-
D) K+ > Cl- > P3- > Ca2+
E) None of these choices are correct.

F) B) and D)
G) A) and E)

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Select the correct electron configuration for Cu (Z = 29) .


A) [Ar]4s23d9
B) [Ar]4s13d10
C) [Ar]4s24p63d3
D) [Ar]4s24d9
E) [Ar]5s24d9

F) B) and D)
G) A) and B)

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In the electron configuration [Ar]4s23d104p4, which are valence electrons?


A) all of the electrons after the [Ar]
B) only the 4s2 electrons
C) only the 3d10 electrons
D) only the 4p4 electrons
E) both the 4s2 and the 4p4 electrons

F) A) and E)
G) A) and D)

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Select the correct electron configuration for Te (Z = 52) .


A) [Kr]5s25p64d8
B) [Kr]5s25d105p4
C) [Kr]5s24d105p6
D) [Kr]5s24f14
E) [Kr]5s24d105p4

F) C) and D)
G) A) and D)

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The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of


A) Kr.
B) Ni.
C) Fe.
D) Pd.
E) None of these choices are correct.

F) A) and C)
G) C) and D)

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Which of the following elements has the smallest atomic size?


A) Na
B) Ar
C) K
D) Ca
E) Kr

F) A) and E)
G) A) and D)

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In a single atom, what is the maximum number of electrons which can have quantum number n = 4?


A) 16
B) 18
C) 32
D) 36
E) None of these choices are correct.

F) C) and D)
G) C) and E)

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First ionization energies of neutral atoms may be positive or negative.

A) True
B) False

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