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Transition elements from the right side of the periodic table are generally found as


A) sulfides because they tend to give up bonding electrons and form crystals with high lattice energies with sulfur.
B) sulfides because their electronegativities favor formation of covalent bonds with the polarizable sulfide anion.
C) oxides because they tend to give up bonding electrons and form crystals with high lattice energies with oxygen.
D) oxides because oxygen, with its high electronegativity, forms strong covalent bonds with them.
E) None of these choices are correct.

F) B) and D)
G) A) and C)

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What gas is produced during the Hall-Héroult process for production of aluminum?


A) chlorine, Cl2
B) oxygen, O2
C) hydrogen, H2
D) ammonia, NH3
E) carbon dioxide, CO2

F) B) and D)
G) None of the above

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The alkali metals are isolated from non-aqueous systems. Why is this necessary?


A) The electrolysis of aqueous solutions of the alkali metals requires more energy than electrolysis of the molten salts.
B) The dissolved alkali earth halides are too reactive to be electrolyzed.
C) The aqueous metal ions are more difficult to reduce than water.
D) The reduction potentials of the alkali metals are more positive than the reduction potential of water.
E) The aqueous metal ions react violently with water.

F) A) and B)
G) A) and C)

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Transition elements from the left side of the periodic table are generally found as


A) sulfides because they tend to give up bonding electrons and form crystals with high lattice energies with sulfur.
B) sulfides because their electronegativities favor formation of covalent bonds with the polarizable sulfide anion.
C) oxides because they tend to give up bonding electrons and form crystals with high lattice energies with oxygen.
D) oxides because oxygen, with its high electronegativity, forms strong covalent bonds with them.
E) the uncombined elements, because they are noble metals.

F) A) and B)
G) A) and D)

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Hydrometallurgy uses __________________ to separate a metal from its ore.


A) solid phase chemical properties
B) electrical processes
C) thermal processes
D) aqueous chemical processes
E) molten salt processes

F) C) and E)
G) A) and B)

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The debris accompanying a mineral is called


A) slag.
B) gangue.
C) ore.
D) halite.
E) ash.

F) None of the above
G) A) and B)

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In the industrial electrolysis of aqueous NaCl (the chlor-alkali process), the modern trend is toward the use of cells incorporating polymer membranes to separate the anode and cathode solutions.

A) True
B) False

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The process of converting metal sulfides to metal oxides is called


A) roasting.
B) smelting.
C) reduction.
D) leaching.
E) oxidation.

F) C) and D)
G) B) and C)

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The atmosphere contains about 700. billion metric tons of carbon in the form of carbon dioxide. In the carbon cycle, about 200. billion metric tons of carbon (as carbon dioxide) enters the atmosphere each year. Assuming that 200. billion metric tons of carbon also leaves the atmosphere annually, how many years does the average carbon atom spend in the atmosphere in each cycle?


A) 0.29 years
B) 3.5 years
C) 500. years
D) 140,000 years
E) More information is needed in order to calculate the answer.

F) A) and B)
G) None of the above

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The Earth's core consists mainly of


A) Ni
B) O
C) Al
D) Si
E) Fe

F) C) and D)
G) All of the above

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Pyrometallurgy uses __________________ to separate a metal from its ore.


A) solid phase chemical properties
B) electrical processes
C) thermal processes
D) aqueous chemical processes
E) explosives

F) None of the above
G) C) and D)

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The kinetic isotope effect is the basis for


A) the radioactivity of tritium.
B) isolation of pure D2O.
C) tritium's high reactivity.
D) the increase in boiling point when comparing hydrogen, deuterium, and tritium.
E) nuclear power generation.

F) B) and D)
G) None of the above

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The Frasch process is used to


A) convert aluminum oxide to metallic aluminum.
B) convert copper ore to copper sulfide.
C) mine magnesium.
D) mine elemental sulfur.
E) produce sodium metal.

F) B) and D)
G) None of the above

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Electrolysis is used as the last step in isolating pure


A) iron.
B) boron.
C) aluminum.
D) selenium.
E) carbon.

F) A) and C)
G) A) and B)

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The most abundant element in the Earth's crust is


A) H
B) Fe
C) Al
D) Si
E) O

F) B) and C)
G) None of the above

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The chlor-alkali process produces chlorine, Cl2(g) , in large quantities. What other industrially important substances are produced in this process?


A) Na(s) , H2(g)
B) H2(g) , O2(g)
C) Hg(l) , NaCl(s)
D) Na(s) , O2(g)
E) NaOH(aq) , H2(g)

F) A) and B)
G) D) and E)

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The main effect of the biosphere on the chemistry of the Earth's crust has been to


A) create a reducing atmosphere.
B) create an oxidizing atmosphere.
C) increase the relative humidity.
D) decrease the relative humidity.
E) increase the level of atmospheric carbon dioxide.

F) A) and D)
G) A) and C)

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When nitrogen undergoes atmospheric fixation, it enters the sea and land in the form of


A) NO.
B) NO2.
C) NH3.
D) NO3-.
E) NH4+.

F) All of the above
G) A) and B)

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The industrial production of ammonia from nitrogen and hydrogen accounts for a greater amount of nitrogen fixation than either the atmospheric or the biological pathways.

A) True
B) False

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The purpose of anodizing aluminum is to remove the oxide layer from the metal's surface.

A) True
B) False

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