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In order to be a Brønsted-Lowry base, a species must contain a proton.

A) True
B) False

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Select the pair of substances that is not a conjugate acid-base pair.


A) H3O+, H2O
B) HNO2, NO2-
C) H2SO4, HSO4-
D) H2S, S2-
E) NH3, NH2-

F) C) and D)
G) None of the above

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Which one of the following substances will give an aqueous solution of pH closest to 7?


A) KNO3
B) CO2
C) NH4I
D) NH3
E) CH3NH2

F) D) and E)
G) A) and B)

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The substance HClO4 is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) A) and C)
G) A) and D)

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Which of the following pairs has the stronger acid listed first?


A) HBr, HI
B) HClO2, HClO3
C) H2SeO4, H2SeO3
D) HNO2, HNO3
E) HF, HCl

F) A) and B)
G) B) and C)

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All Lewis acids contain at least one proton.

A) True
B) False

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What is the value of Ka for the methylammonium ion, CH3NH3+? Kb(CH3NH2) = 4.4 × 10-4


A) 4.4 × 10-4
B) 4.8 × 10-6
C) 4.4 × 10-10
D) 2.3 × 10-11
E) 4.4 × 10-18

F) C) and D)
G) A) and B)

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A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? H2C2O4(aq) + H2PO4(aq) A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>(aq)  + H<sub>2</sub>PO<sub>4</sub>(aq)    HC<sub>2</sub>O<sub>4</sub>(aq)  + H<sub>3</sub>PO<sub>4</sub>(aq)  A)  Oxalic acid is a weaker acid than phosphoric acid. B)  The hydrogen oxalate anion, HC<sub>2</sub>O<sub>4</sub>, is a stronger base than the dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub>. C)  Phosphoric acid is a weaker acid than oxalic acid. D)  The dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub><sup>-</sup>, is a stronger acid than oxalic acid. E)  Water is a stronger acid than either oxalic or phosphoric acids. HC2O4(aq) + H3PO4(aq)


A) Oxalic acid is a weaker acid than phosphoric acid.
B) The hydrogen oxalate anion, HC2O4, is a stronger base than the dihydrogen phosphate anion, H2PO4.
C) Phosphoric acid is a weaker acid than oxalic acid.
D) The dihydrogen phosphate anion, H2PO4-, is a stronger acid than oxalic acid.
E) Water is a stronger acid than either oxalic or phosphoric acids.

F) A) and E)
G) C) and E)

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Which of the following acids has the lowest pH? 0.1 M HBO, pKa = 2.43 0) 1 M HA, pKa = 4.55 0) 1 M HMO, pKa = 8.23 0) 1 M HST, pKa = 11.89 Pure water


A) HA
B) HST
C) HMO
D) HBO
E) pure water

F) All of the above
G) A) and B)

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The hydrated Al3+ ion, Al(H2O) 63+, is a weak acid in water. What are the products of its reaction with H2O? Al(H2O) 63+(aq) + H2O(l) → ?


A) Al(H2O) 5OH2+(aq) + H3O+(aq)
B) Al(H2O) 6H4+(aq) + OH-(aq)
C) Al(H2O) 53+(aq) + 2H2O(l)
D) Al(H2O) 6OH2+(aq) + H3O+(aq)
E) Al(H2O) 62+(aq) + H3O+(aq)

F) A) and B)
G) None of the above

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A solution is prepared by adding 0.10 mol of iron(III) nitrate, Fe(NO3) 3, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The value of Ka for the species in solution must be known before a prediction can be made.
E) The value of Kb for the species in solution must be known before a prediction can be made.

F) A) and E)
G) A) and D)

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The substance HCl is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) C) and E)
G) A) and D)

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According to Brønsted and Lowry, which one of the following is not a conjugate acid-base pair?


A) H3O+/OH-
B) CH3OH2+/CH3OH
C) HI/I-
D) HSO4-/SO42-
E) H2/H-

F) A) and E)
G) C) and E)

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Iodine trichloride, ICl3, will react with a chloride ion to form ICl4-. Which species, if any, acts as a Lewis acid this reaction?


A) ICl4-
B) ICl3
C) Cl-
D) the solvent
E) None of these choices are correct.

F) A) and D)
G) A) and C)

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The substance H2SO3 is considered


A) a weak Arrhenius base.
B) a strong Arrhenius acid.
C) a strong Arrhenius base.
D) a neutral compound.
E) a weak Arrhenius acid.

F) C) and E)
G) C) and D)

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The substance HOBr is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) A) and B)
G) A) and C)

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Which one of the following is a Lewis acid but not a Brønsted-Lowry acid?


A) Fe3+
B) H3O+
C) HSO4-
D) NH3
E) H2O

F) A) and B)
G) All of the above

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Select the strongest acid from the following list.


A) HBrO4
B) HClO
C) HBrO2
D) HBrO
E) HIO

F) A) and B)
G) A) and E)

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Which one of the following is a strong acid?


A) H2CO3
B) H2SO3
C) H2SO4
D) H3PO4
E) CH3COOH

F) A) and B)
G) A) and C)

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An aqueous solution is considered to be acidic if


A) the hydroxide ion concentration is 10-6 M.
B) the hydrogen ion concentration is 10-8 M.
C) the hydroxide and hydrogen ion concentrations are equal.
D) the hydroxide ion concentration is greater than the hydrogen ion concentration.
E) the hydroxide ion concentration is 10-10 M.

F) A) and B)
G) B) and E)

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