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Draw and name all of the isomers for C4H8.

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blured image 1-butene; 2-butene ...

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Alcohols used as a gasoline additive or substitute are often called biofuels. Similar organic compounds derived from vegetable oils and fats are called biodiesels, which are not alcohols but another class of organic chemicals called esters. Qualitatively compare the combustion energy content (kJ/g) of the four-carbon alcohol, butanol (CH3CH2CH2CH2OH) , with the energy content (kJ/g) of the four-carbon ester, ethyl acetate (CH3COOCH2CH3) .


A) Ethyl acetate has less energy/mass than butanol.
B) Ethyl acetate has more energy/mass than butanol.
C) The two compounds have roughly the same energy/mass.
D) These are not two different compounds and so must have the same energy/mass.
E) There is no basis for determining this without some form of enthalpy values.

F) C) and D)
G) B) and D)

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The C-C-C bond angles in octane (CH3CH2CH2CH2CH2CH2CH2CH3) are ________


A) 180°.
B) 120°.
C) 90°.
D) 109.5°.
E) 60°.

F) C) and D)
G) C) and E)

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A subunit of an organic compound that confers particular chemical and physical properties is termed ________


A) a monomer.
B) an oligomer.
C) a functional group.
D) a synthetic unit.
E) an isomer.

F) C) and E)
G) C) and D)

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Which of the following structures represents cyclohexene?


A) Which of the following structures represents cyclohexene? A)    B)    C)    D)
B) Which of the following structures represents cyclohexene? A)    B)    C)    D)
C) Which of the following structures represents cyclohexene? A)    B)    C)    D)
D) Which of the following structures represents cyclohexene? A)    B)    C)    D)

E) B) and D)
F) A) and B)

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How many structural isomers (also called constitutional isomers) are there for propylene, and why?


A) two, because of resonance
B) two, because of geometrical isomerism
C) two, because the double bond can be in either one of two locations
D) none, because the two skeletal structures can be superimposed
E) none, because double bonds always occur on the right in alkenes

F) C) and E)
G) A) and E)

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Rank the following according to their fuel values in order of increasing energy/mass. C8H18; CO; CH3OH; CH3OCH3


A) CO < CH3OCH3 < CH3OH < C8H18
B) CH3OCH3 < CO < CH3OH < C8H18
C) CO < CH3OH < CH3OCH3 < C8H18
D) C8H18 < CO < CH3OH < CH3OCH3
E) C8H18 < CH3OCH3 < CH3OH < CO

F) C) and E)
G) None of the above

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A compound composed solely of carbon and hydrogen that is unsaturated must be ________


A) an alkane.
B) an alkene.
C) an alkyne.
D) either an alkane or an alkene.
E) either an alkene or an alkyne.

F) A) and B)
G) B) and D)

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What is the molecular formula for the compound illustrated below? What is the molecular formula for the compound illustrated below?   A)  C<sub>5</sub>H<sub>7</sub> B)  C<sub>5</sub>H<sub>8</sub> C)  C<sub>5</sub>H<sub>9</sub> D)  C<sub>5</sub>H<sub>10</sub> E)  C<sub>5</sub>H<sub>5</sub>


A) C5H7
B) C5H8
C) C5H9
D) C5H10
E) C5H5

F) A) and B)
G) None of the above

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What is the molecular formula for the following compound? What is the molecular formula for the following compound?   A)  C<sub>4</sub>H<sub>5</sub>O<sub>2</sub> B)  C<sub>4</sub>H<sub>6</sub>O<sub>2</sub> C)  C<sub>4</sub>H<sub>7</sub>O<sub>2</sub> D)  C<sub>4</sub>H<sub>8</sub>O<sub>2</sub> E)  C<sub>4</sub>H<sub>10</sub>O<sub>2</sub>


A) C4H5O2
B) C4H6O2
C) C4H7O2
D) C4H8O2
E) C4H10O2

F) B) and D)
G) A) and E)

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The characteristic "fishy" odor comes from methylamine (CH3NH2) , which is similar to ammonia (NH3) in structure and also in its ability to react with acids as a weak base. Why would the acid form of methylamine not have as strong an odor as methylamine?


A) because it would decompose to methane and ammonia
B) because it would not be volatile as a polyatomic ion
C) because it would melt in the acid
D) because it would decompose to carbon, hydrogen, and nitrogen
E) because it would have a different three-dimensional structure

F) C) and D)
G) A) and E)

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The C-O-C bonding arrangement is called the ________ functional group.


A) alcohol
B) ester
C) amine
D) ether
E) carbonyl

F) C) and D)
G) B) and C)

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The monomer for polystyrene is shown below. Which of the bonds is involved in the polymerization process? The monomer for polystyrene is shown below. Which of the bonds is involved in the polymerization process?   A)  I only B)  II only C)  III only D)  IV only E)  Bonds I-IV are all involved in polymerization.


A) I only
B) II only
C) III only
D) IV only
E) Bonds I-IV are all involved in polymerization.

F) A) and D)
G) A) and C)

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A hydrocarbon is a compound that contains ________


A) carbon with hydrogen and oxygen in the ratio 2:1.
B) carbon with hydrogen and oxygen in any ratio.
C) only carbon and hydrogen.
D) carbon, hydrogen, and any functional groups.
E) carbon and any other elements.

F) A) and E)
G) A) and D)

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Which of these is not a condensation polymer?


A) spandex
B) nylon
C) PETE
D) poly(propylene)
E) polyester

F) B) and D)
G) A) and C)

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What are the similarities and differences between structural (constitutional) isomers, geometric (stereo) isomers, and optical isomers?

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The molecules that comprise structural, ...

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Name the compound with the structural formula CH3(CH2) 16CH3.


A) n-octane
B) n-hexadecane
C) n-octadecane
D) n-decane
E) 1,16-dimethylhexadecane

F) B) and D)
G) All of the above

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Gasoline additives such as ethanol are employed to ________


A) decrease odor.
B) promote complete combustion.
C) decrease octane rating.
D) make the fuel less volatile.
E) increase fuel value.

F) B) and D)
G) None of the above

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Delocalized bonding in aromatic hydrocarbons is possible because of ________


A) the fact that electrons can move very quickly from one resonance form to another.
B) adjacent 2pz orbitals each having one electron.
C) Wade's rules.
D) double-headed arrows.
E) Cooper pairs.

F) A) and B)
G) A) and D)

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An alkyne is characterized by a ________ bond between carbon atoms that have a ________ local molecular geometry and ________ hybridization.


A) single; linear; sp
B) single; linear; sp3
C) double; trigonal planar; sp2
D) double; tetrahedral; sp3
E) triple; linear; sp

F) None of the above
G) B) and C)

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