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Transition elements from the left side of the periodic table are generally found as


A) sulfides because they tend to give up bonding electrons and form crystals with high lattice energies with sulfur.
B) sulfides because their electronegativities favor formation of covalent bonds with the polarizable sulfide anion.
C) oxides because they tend to give up bonding electrons and form crystals with high lattice energies with oxygen.
D) oxides because oxygen, with its high electronegativity, forms strong covalent bonds with them.
E) the uncombined elements, because they are noble metals.

F) A) and B)
G) All of the above

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The final step of the purification of copper involves electrorefining in which copper is separated from nickel and iron by being reduced at the cathode of a cell. Why are nickel and iron not reduced?


A) Their reduction potentials are more positive than copper's.
B) Their reduction potentials are more negative than copper's.
C) They cannot be deposited on a copper electrode.
D) Their reduction potentials are more negative than water's.
E) Their reduction requires large overvoltages.

F) B) and E)
G) A) and C)

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B

Nitrogen fixation occurs through atmospheric, industrial, and biological processes. Which of these fixes the most nitrogen?


A) biological
B) atmospheric
C) industrial
D) industrial \approx atmospheric
E) industrial \approx biological

F) B) and E)
G) C) and E)

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Compared to the asbestos diaphragm-cell used in the chlor-alkali process, list A) one main advantage and one disadvantage of mercury cells. B) two important advantages of polymer membrane-cells.

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a. Purer NaOH product is forme...

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The main effect of the biosphere on the chemistry of the earth's crust has been to


A) create a reducing atmosphere.
B) create an oxidizing atmosphere.
C) increase the relative humidity.
D) decrease the relative humidity.
E) increase the level of atmospheric carbon dioxide.

F) All of the above
G) B) and E)

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B

Plants extract phosphate from the soil


A) by converting it to the dihydrogen phosphate ion by addition of acid to the soil near roots.
B) by converting it to phosphoric acid.
C) by osmosis.
D) by leaching.
E) by fixation.

F) C) and D)
G) A) and E)

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The process that selectively extracts a metal from its ore, by dissolving it, is called


A) roasting.
B) leaching.
C) smelting.
D) flotation.
E) hydration.

F) A) and B)
G) B) and C)

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The most abundant element in the Earth's crust is:


A) H
B) Fe
C) Al
D) Si
E) O

F) All of the above
G) B) and D)

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The bond energy in the hydrogen molecule (H2) is greater than that of the tritium molecule (T2).

A) True
B) False

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The process used to produce silicon with a purity of more than 99.999999% is called


A) zone refining.
B) electrorefining.
C) distillation.
D) sublimation.
E) alloying.

F) B) and D)
G) None of the above

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The process in which a gaseous substance is converted into a condensed, more usable chemical substance is called


A) differentiation.
B) liquefaction.
C) fixation.
D) deposition.
E) remediation.

F) A) and E)
G) C) and D)

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Lightning, fires and other atmospheric processes result in the formation of nitric acid, HNO3, from atmospheric N2, O2 and H2O. Write balanced chemical equations to represent the three reactions involved in the formation of HNO3 by this route.

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The most common source for commercial production of aluminum is called


A) aluminite.
B) hematite.
C) galena.
D) cinnabar.
E) bauxite.

F) A) and E)
G) C) and D)

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The alkali metals are isolated from non-aqueous systems. Why is this necessary?


A) The electrolysis of aqueous solutions of the alkali metals requires more energy than electrolysis of the molten salts.
B) The dissolved alkali earth halides are too reactive to be electrolyzed.
C) The aqueous metal ions are more difficult to reduce than water.
D) The reduction potentials of the alkali metals are more positive than the reduction potential of water.
E) The aqueous metal ions react violently with water.

F) A) and D)
G) B) and E)

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.

A) True
B) False

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The purpose of anodizing aluminum is to remove the oxide layer from the metal's surface.

A) True
B) False

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False

What elements are alloyed to make stainless steel?


A) Fe and C
B) Fe and Mn
C) Fe and Ni
D) Fe and Ni.
E) Fe, Cr and Ni

F) All of the above
G) A) and B)

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Which of the following reactions is a good small-scale laboratory method for preparation of hydrogen?


A) CH4(g) + H2O(g) \rightarrow CO(g) + 3H2(g)
B) 3FeCl2(s) + 4H2O(g) \rightarrow Fe3O4(s) + 6HCl(g) + H2(g)
C) NaH(s) + H2O(l) \rightarrow NaOH(aq) + H2(g)
D) CO(g) + H2O(g) \rightarrow CO2(g) + H2(g)
E) None of these methods is useful.

F) All of the above
G) A) and B)

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The kinetic isotope effect is the basis for


A) the radioactivity of tritium.
B) isolation of pure D2O.
C) tritium's high reactivity.
D) the increase in boiling point when comparing hydrogen, deuterium and tritium.
E) nuclear power generation.

F) C) and D)
G) A) and B)

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Potassium is produced industrially by the reaction Na(l) + K+(l)  Potassium is produced industrially by the reaction Na(l) + K<sup>+</sup>(l)   Na<sup>+</sup>(l) + K(g). The reaction is carried out at 850 \degree C, but the equilibrium K<sub>c</sub> constant strongly favors the reactants. Explain how the conditions are manipulated to ensure a good yield of potassium despite the small value of K<sub>c</sub>.  Na+(l) + K(g). The reaction is carried out at 850 °\degree C, but the equilibrium Kc constant strongly favors the reactants. Explain how the conditions are manipulated to ensure a good yield of potassium despite the small value of Kc.

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The gaseous potassium product ...

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