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Alloying a metal is done to


A) make its extraction from its ore easier.
B) convert the metal to an oxide.
C) disguise the true identity of the metal.
D) prepare ultrapure metal samples.
E) enhance properties like conductivity.

F) A) and E)
G) A) and D)

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Cryolite, Na3AlF6, is used in the electrolysis of aluminum oxide because


A) it is a good source of fluoride ions.
B) it reduces the energy requirement of the process, due to its low melting point.
C) it provides a source of fluorine, an oxidizing agent.
D) it provides a source of sodium, a reducing agent.
E) it is very soluble in water.

F) C) and D)
G) A) and D)

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Hydrogen displays the largest kinetic isotope effect of all the elements.

A) True
B) False

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The debris accompanying a mineral is called


A) slag.
B) gangue.
C) ore.
D) halite.
E) ash.

F) B) and E)
G) B) and D)

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The Frasch process is used to


A) convert aluminum oxide to metallic aluminum.
B) convert copper ore to copper sulfide.
C) mine magnesium.
D) mine elemental sulfur.
E) produce sodium metal.

F) A) and D)
G) A) and C)

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Sulfide ores are frequently treated by flotation in order to concentrate them.

A) True
B) False

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Describe, and give reasons for, the fundamental bonding differences between transition metal sulfides and transition metal oxides.

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Transition metal oxides are ionic in nat...

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The main end use of sulfuric acid is


A) manufacture of iron and steel
B) processing of petroleum
C) production of fertilizers
D) production of explosives
E) production of various other chemicals

F) B) and D)
G) A) and B)

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What gas is produced at the anode in the Hall-Héroult process for the electrolytic production of aluminum?

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The industrial production of ammonia from nitrogen and hydrogen accounts for a greater amount of nitrogen fixation than either the atmospheric or the biological pathways.

A) True
B) False

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Carbon atoms in the carbon cycle spend most of their time in the oceans.

A) True
B) False

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When nitrogen undergoes atmospheric fixation, it enters the sea and land in the form of:


A) NO
B) NO2
C) NH3
D) NO3¯
E) NH4+

F) B) and C)
G) A) and B)

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The Downs cell is used in the production of


A) copper.
B) hydrogen.
C) iron.
D) magnesium.
E) sodium.

F) A) and B)
G) A) and E)

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The Hall-Héroult process refers to


A) the production of aluminum by electrolysis.
B) the recovery of sulfur from underground deposits.
C) the manufacture of sulfuric acid.
D) the production of ammonia from nitrogen and hydrogen gases.
E) the isolation of Al2O3 from bauxite.

F) A) and E)
G) A) and B)

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Electrometallurgy uses _________________ to separate a metal from its ore.


A) solid phase chemical properties
B) electrical processes
C) thermal processes
D) aqueous chemical processes
E) molten salt processes

F) A) and B)
G) A) and C)

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Transition elements from the right side of the periodic table are generally found as


A) sulfides because they tend to give up bonding electrons and form crystals with high lattice energies with sulfur.
B) sulfides because their electronegativities favor formation of covalent bonds with the polarizable sulfide anion.
C) oxides because they tend to give up bonding electrons and form crystals with high lattice energies with oxygen.
D) oxides because oxygen, with its high electronegativity, forms strong covalent bonds with them.
E) None of these choices is correct.

F) C) and D)
G) A) and E)

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Give two important reasons why there is so much more Na+ in the oceans than K+, despite their similar abundances in the earth's crust.

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Clays bind K+ more effectively ...

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The chlor-alkali process produces chlorine, Cl2(g) , in large quantities. What other industrially important substances are produced in this process?


A) Na(s) , H2(g)
B) H2(g) , O2(g)
C) Hg(l) , NaCl(s)
D) Na(s) , O2(g)
E) NaOH(aq) , H2(g)

F) B) and E)
G) A) and C)

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The process of converting metal sulfides to metal oxides is called


A) roasting.
B) smelting.
C) reduction.
D) leaching.
E) oxidation.

F) A) and E)
G) B) and D)

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In the commercial production of aluminum metal, the final stage involves the reaction 2Al2O3(in molten Na3AlF6) + 3C(graphite) \rightarrow 4Al(l) + 3CO2(g) Briefly outline the method and equipment with which the reaction is accomplished.

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This is done electrolytically,...

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