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Select the element whose Lewis symbol is correct.


A) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
B) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
C) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
D) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
E) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)

F) D) and E)
G) B) and E)

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Which of the following period 3 chlorides would be expected to have the highest melting point?


A) MgCl 2
B) AlCl 3
C) SiCl 4
D) PCl 3
E) SCl 2

F) B) and E)
G) B) and D)

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Which of the following contains covalent bonds?


A) BaO
B) IBr
C) Mg
D) LiBr
E) Cu

F) A) and C)
G) C) and D)

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The lattice energy is the energy released when separated ions in the gas phase combine to form ionic molecules in the gas phase.

A) True
B) False

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Hydrogenation of double and triple bonds is an important industrial process. Calculate (in kJ) the standard enthalpy change ΔH° for the hydrogenation of ethyne (acetylene) to ethane. H-C≡C-H(g) + 2H2(g) → H3C-CH3(g) Hydrogenation of double and triple bonds is an important industrial process. Calculate (in kJ)  the standard enthalpy change ΔH° for the hydrogenation of ethyne (acetylene)  to ethane. H-C≡C-H(g)  + 2H<sub>2</sub>(g)  → H<sub>3</sub>C-CH<sub>3</sub>(g)    A) −296 kJ B) −51 kJ C) 51 kJ D) 296 kJ E) 381 kJ


A) −296 kJ
B) −51 kJ
C) 51 kJ
D) 296 kJ
E) 381 kJ

F) C) and D)
G) C) and E)

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When two atoms form a covalently-bonded diatomic molecule, the distance between the nuclei at which the potential energy is at a minimum is called


A) the bond energy.
B) the bond length.
C) the molecular diameter.
D) the covalent radius.
E) the covalent diameter.

F) C) and E)
G) A) and B)

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Combustion of a fat will release more energy than combustion of an equal mass of carbohydrate because


A) fats contain more bonds to oxygen than carbohydrates.
B) fats contain fewer bonds to oxygen than carbohydrates.
C) the total energy of the carbon-carbon and carbon-hydrogen bonds in fats is greater than the energy content of the carbon-oxygen and oxygen-hydrogen bonds in the reaction products (carbon dioxide and water) .
D) the total energy of the carbon-carbon and carbon-hydrogen bonds in fats is greater than the energy content of the bonds in carbohydrates.
E) fats have higher molar masses than carbohydrates.

F) C) and D)
G) A) and B)

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Arrange calcium, rubidium, sulfur, and arsenic in order of decreasing electronegativity.


A) S > As > Rb > Ca
B) S > As > Ca > Rb
C) As > S > Rb > Ca
D) As > S > Ca > Rb
E) None of these choices are correct.

F) B) and C)
G) C) and D)

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Quartz (SiO2) is a solid with a melting point of 1550 °C. The bonding in quartz is best described as


A) lattice energy.
B) network attractions.
C) ionic bonding.
D) covalent bonding.
E) metallic bonding.

F) B) and D)
G) A) and E)

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The majority of elements are good electrical conductors when in solid form.

A) True
B) False

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Analysis of an unknown substance showed that it has a high boiling point and is brittle. It is an insulator as a solid but conducts electricity when melted. Which of the following substances would have those characteristics?


A) HCl
B) Al
C) KBr
D) SiF 4
E) I 2

F) B) and E)
G) A) and D)

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Electronegativities on Pauling's scale are calculated from ionization energies and electron affinities.

A) True
B) False

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The melting points of metals are only moderately high because


A) metallic bonding is weak.
B) metals have fewer bonding electrons than nonmetals.
C) metals also have relatively low boiling points.
D) the melting process does not break the metallic bonds.
E) metals prefer to be bonded to nonmetals.

F) All of the above
G) D) and E)

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Which of the following elements is the most electronegative?


A) S
B) Ru
C) Si
D) Te
E) Cs

F) C) and D)
G) A) and B)

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Select the element whose Lewis symbol is correct.


A) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
B) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
C) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
D) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)
E) Select the element whose Lewis symbol is correct. A)    B)    C)    D)    E)

F) B) and D)
G) None of the above

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In which of the following processes does the enthalpy change (ΔH) directly represent the magnitude of the lattice energy of KCl(s) ?


A) Cl 2(g) + 2K(s) → 2KC (s)
B) KCl(s) → K +(aq) + Cl (aq)
C) KCl(s) → K +(g) + Cl (g)
D) KCl(s) → K(s) + Cl (g)
E) KCl(s) → K(s) + Cl(g)

F) C) and E)
G) D) and E)

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The diameter of a chloride ion is 362 pm, and the diameter of a potassium ion is 276 pm. What is the distance between the nuclei of adjacent chloride and potassium ions in solid potassium chloride?


A) 1276 pm
B) 638 pm
C) 319 pm
D) 181 pm
E) 138 pm

F) B) and D)
G) A) and E)

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The lattice energy of MgCl2 is the energy change for which one of the following processes?


A) Mg( s) + Cl 2( g) → MgCl 2( s)
B) Mg( g) + 2Cl( g) → MgCl 2( s)
C) Mg 2+( s) + 2Cl ( g) → MgCl 2( g)
D) Mg 2+( g) + 2Cl ( g) → MgCl 2( s)
E) MgCl 2( aq) → MgCl 2( s)

F) A) and B)
G) A) and C)

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Which one of the following properties is least characteristic of typical ionic compounds?


A) High melting point
B) High boiling point
C) Brittleness
D) Poor electrical conductor when solid
E) Poor electrical conductor when molten

F) A) and E)
G) C) and D)

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Select the correct formula for a compound formed from barium and nitrogen.


A) BaN
B) BaN 2
C) Ba 2N 3
D) Ba 2N
E) Ba 3N 2

F) C) and E)
G) None of the above

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