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The rate constant of the reaction Cl + CHCl3 → HCl + CCl3 is 5.8 × 107 M-1 s-1 at 25°C and has an activation energy of 11.0 kJ/mol. Calculate the rate constant for this reaction in the lower stratosphere where the temperature is -57°C.


A) 1.1 × 107 M-1 s-1
B) 4.2 × 107 M-1 s-1
C) 4.9 × 109 M-1 s-1
D) 9.5 × 106 M-1 s-1
E) 2.7 × 109 M-1 s-1

F) A) and B)
G) C) and D)

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Nitrogen fixation occurs through atmospheric, industrial, and biological processes. Which of these fixes the most nitrogen?


A) biological
B) atmospheric
C) industrial
D) industrial ≈ atmospheric
E) industrial ≈ biological

F) B) and C)
G) A) and B)

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When radon decays it produces Po-214 and Po-218. This means that


A) a gas (radon) is converted into a solid (Po) .
B) radon decays into nonhazardous products.
C) after the decay there is no danger due to radioactivity.
D) the polonium can be swept out of the basement.
E) None of these choices.

F) All of the above
G) B) and C)

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________ is the layer of the atmosphere closest to the surface of the Earth.

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Acid rain is precipitation having a pH that is


A) above 7.
B) below 5.5.
C) below 7.
D) above 8.6.
E) above 10.

F) B) and E)
G) B) and D)

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Nitric acid is converted to ________ in the soil.

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Name four "greenhouse gases" besides carbon dioxide.

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methane, n...

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What colors do excited nitrogen molecules emit?

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Ozone


A) dissociates to O and O2 by absorbing UV energy.
B) is formed by the combination of oxygen atoms with O2 molecules.
C) can be destroyed by chlorine atoms that result from the decomposition of chlorocarbons in the stratosphere.
D) All of the choices are correct.
E) None of these choices.

F) A) and E)
G) A) and C)

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What is the layer of the atmosphere called which consists of nitrogen, oxygen, and ozone and the air temperature decreases with increasing altitude?


A) outer atmosphere
B) mesosphere
C) thermosphere
D) troposphere
E) stratosphere

F) A) and E)
G) None of the above

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Which of these species is not an acidic oxide?


A) P4O10
B) P4O6
C) SO3
D) CO
E) SiO2

F) B) and D)
G) C) and D)

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How is atmospheric oxygen removed from the environment?

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through respiration ...

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Which below is a CFC?


A) CFCl3
B) CF2Cl2
C) C2F3Cl3
D) All of the choices are correct.
E) None of these choices is correct.

F) A) and D)
G) B) and E)

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Write chemical equations that show what happens when acid rain reacts with limestone rock.

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CaCO3 + 2H+ ...

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Choose the incorrect statement concerning radon gas.


A) Radon gas is found at home.
B) Radon is a noble gas.
C) Radon accounts for 3/4 of the Earth's background radioactivity.
D) Radon-222 is the most hazardous form of radon due to a half-life of 3.8 days.

E) B) and D)
F) A) and B)

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Write out the steps in the mechanism by which ozone is formed in the stratosphere.

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O2(g) + hv ...

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________ is the biological or industrial conversion of molecular nitrogen into nitrogen compounds.

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Chlorofluorocarbons diffuse in the troposphere where they begin to decompose allowing the chlorine atoms to break down ozone.


A) True
B) False

C) A) and B)
D) undefined

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The gases spewed into the atmosphere when a volcano erupts are N2, H2S, HCl, HF, CO2, and water vapor.

A) True
B) False

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Ozone protects us from ultraviolet light by


A) reflecting the light from the ozone layer.
B) reacting with oxygen atoms to form O2.
C) dissociating into O2 and oxygen atoms.
D) None of these choices.

E) C) and D)
F) B) and C)

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