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Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)


A) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
B) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
C) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
D) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
E) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH. Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)

F) A) and B)
G) B) and E)

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Write the ion product expression for calcium phosphate, Ca3(PO4) 2.


A) Write the ion product expression for calcium phosphate, Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E)  (3 × [Ca<sup>2+</sup>]) (2 × [PO<sub>4</sub><sup>3-</sup> ]
B) Write the ion product expression for calcium phosphate, Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E)  (3 × [Ca<sup>2+</sup>]) (2 × [PO<sub>4</sub><sup>3-</sup> ]
C) Write the ion product expression for calcium phosphate, Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E)  (3 × [Ca<sup>2+</sup>]) (2 × [PO<sub>4</sub><sup>3-</sup> ]
D) Write the ion product expression for calcium phosphate, Ca<sub>3</sub>(PO<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E)  (3 × [Ca<sup>2+</sup>]) (2 × [PO<sub>4</sub><sup>3-</sup> ]
E) (3 × [Ca2+]) (2 × [PO43- ]

F) A) and C)
G) C) and D)

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Calculate the pH at the equivalence point for the titration of 50.0 mL of 0.20 M NH3 with 0.20 M HCl. [Kb(NH3) = 1.8 × 10-5]


A) 2.87
B) 4.98
C) 5.13
D) 7.00
E) 11.13

F) A) and E)
G) D) and E)

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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH) buffer that has a pH of 4.77. Ka = 1.7 × 10-4

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Prepare a solution h...

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You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH) and 0.20 M sodium acetate (CH3COONa) . What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka(CH3COOH) = 1.8 × 10-5]


A) 4.65
B) 4.71
C) 4.56
D) 4.84
E) 5.07

F) B) and C)
G) A) and E)

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What is the name used to describe the situation when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium which shifts the equilibrium?


A) Shift ion
B) Shift reagent
C) Equilibrium ion
D) Common ion effect
E) Ion adduct

F) C) and E)
G) A) and D)

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A 20.00-mL sample of 0.3000 M HBr is titrated with 0.15 M NaOH. What is the pH of the solution after 40.3 mL of NaOH have been added to the acid?


A) 1.00
B) 3.13
C) 10.87
D) 11.05
E) 13.14

F) B) and E)
G) A) and B)

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Will a precipitate (ppt) form when 20.0 mL of 1.1 × 10-3 M Ba(NO3) 2 are added to 80.0 mL of 8.4 × 10-4M Na2CO3?


A) Yes, the ppt is Ba(NO3) 2.
B) Yes, the ppt is NaNO3.
C) Yes, the ppt is BaCO3.
D) Yes, the ppt is Na2CO3.
E) No, a precipitate will not form.

F) None of the above
G) B) and D)

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Which is more soluble in a basic solution than in pure water?


A) AgF
B) AgCN
C) CO2
D) NaCl
E) CH3COOK

F) D) and E)
G) A) and B)

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The amount of strong acid added to a buffer solution cannot exceed the original amount of conjugate base present in order for the buffer to still work.

A) True
B) False

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pH = pKa + log [conjugate base]/[weak acid] is the ________-________ equation.

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Henderson-...

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Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH. Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid HA with a 0.100 M solution of NaOH.   What is the approximate pK<sub>a</sub> of HA? A)  4 B)  6 C)  8 D)  9 E)  12 What is the approximate pKa of HA?


A) 4
B) 6
C) 8
D) 9
E) 12

F) B) and D)
G) A) and B)

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NaCl is added slowly to a solution that is 0.010 M each in Cu+, Ag+, and Au+. The Ksp for CuCl, AgCl, and AuCl are 1.9 × 10-7, 1.8 × 10-10, and 2.0 × 10-13, respectively. Which compound will precipitate first?

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A buffer is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH. What is the pH of this buffer? [Ka(CH3COOH) = 1.8 × 10-5]


A) 4.57
B) 4.52
C) 4.87
D) 4.92
E) 4.97

F) A) and B)
G) All of the above

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The "p" of the pH equation and pKa equation represents ________.

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When the concentration of the conjugate base of a weak acid is less than the concentration of the weak acid in a buffer solution, the pH of the solution is


A) lower than the pKa.
B) higher than the pKa.
C) always acidic.
D) always basic.
E) equal to the pKa.

F) D) and E)
G) C) and E)

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After 50.0 mL of a 0.100 M solution of NaOH is added to 50.0 mL of a 0.100 M solution of an unknown acid, the equilibrium pH is basic. What may be concluded about the identity of the acid?


A) The acid can only be a strong monoprotic acid.
B) The acid can only be a weak monoprotic acid.
C) The acid must be a strong acid, but could be either monoprotic, diprotic, or polyprotic.
D) The acid must be a weak acid, but could be either monoprotic, diprotic, or polyprotic.
E) The acid could be either a strong or weak acid, and could be either a monoprotic, diprotic, orpolyprotic acid.

F) B) and E)
G) D) and E)

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When an acid, HA, is titrated with 0.1 M NaOH, the pH at the half equivalence point of the titration is 4.5. What is the Ka of the acid?


A) 3.2 x 10-5
B) 3.2 x 10-10
C) 1.8 x 10-3
D) 7.0 x 10-7
E) HA is a strong acid

F) A) and E)
G) All of the above

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The endpoint is used to estimate the equivalence point.

A) True
B) False

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What name is given to a solution that contains a weak acid and its conjugate base?

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