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Which is the best acid to prepare a buffer with the lowest pH?


A) C5H5O5COOH, Ka = 4.0 × 10-6
B) HOC6H4OCOOH, Ka = 1.0 × 10-3
C) HBrO, Ka = 2.3 × 10-9
D) C6H4(COOH) 2, Ka = 2.9 × 10-4
E) CH3COOH, Ka = 1.8 × 10-5

F) A) and B)
G) A) and C)

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Calculate the solubility of zinc hydroxide, Zn(OH) 2, in 1.00 M NaOH. Ksp= 3.0 × 10-16 for Zn(OH) 2, Kf = 3.0 × 1015 for Zn(OH) 42-.


A) 0.60 M
B) 0.52 M
C) 0.37 M
D) 0.32 M
E) 0.24 M

F) A) and B)
G) A) and C)

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Which of the following acids is the best acid to prepare a buffer with the highest pH?


A) C5H5O5COOH, Ka = 4.0 × 10-6
B) HOC6H4OCOOH, Ka = 1.0 × 10-3
C) HBrO, Ka = 2.3 × 10-9
D) C6H4(COOH) 2, Ka = 2.9 × 10-4
E) CH3COOH, Ka = 1.8 × 10-5

F) A) and E)
G) B) and D)

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A wildlife biologist is interested in testing the pH of the water in a lake. He obtains a 200.0-mL sample of the water and titrates this sample with a 0.050 M NaOH solution. Neutralization of the lake water requires 40.0 mL of the NaOH solution. Is the lake acidic, basic, or neutral?

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Suppose 3.0 ×10-3 mol of NaOH are added to 6.0 ×10-3 mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10-3 mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)


A) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
B) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
C) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
D) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
E) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA. Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms, and the volume of each box is 1.0 L. Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)

F) A) and B)
G) A) and E)

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Explain why it is important that the amount of added strong acid not exceed the original amount of conjugate base present in the buffer.

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All the added strong acid must...

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At 25°C, the base ionization constant for NH3 is 1.8 × 10-5. Determine the pH of a solution prepared by adding 0.0500 mol of solid ammonium chloride to 100. mL of 0.150 M ammonia.

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What is the concentration of Pb2+ ions in a solution prepared by adding 5.00 g of lead(II) iodide to 500. mL of 0.150 M KI? [Ksp(PbI2) =1.4 × 10-8]


A) 2.2 × 10-2 M
B) 1.5 × 10-7 M
C) 6.2 × 10-7 M
D) 9.3 × 10-8 M
E) 1.4 × 10-8 M

F) A) and E)
G) A) and D)

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The ________ is the point in a titration where the color of the indicator changes.

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Will a precipitate of AgCl form when 0.050 mol NaCl(s) and 0.050 mol AgNO3(s) are dissolved in 500. mL of 3.0 M NH3? (Kf for Ag(NH3)2+ is 1.5 × 107; Ksp(AgCl) = 1.6 × 10-10)

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For a conjugate acid-base pair, Kw = Ka/Kb

A) True
B) False

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A(n) ________ occurs when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium resulting in a shift of the equilibrium to the left.

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Will a precipitate (ppt) form when 300.0 mL of 5.0 × 10-5M AgNO3 are added to 200.0 mL of 2.5 × 10-7M NaBr? Answer yes or no, and identify the precipitate if there is one.


A) Yes, the ppt is AgNO3(s) .
B) Yes, the ppt is AgBr(s) .
C) Yes, the ppt is NaBr(s) .
D) Yes, the ppt is NaNO3(s) .
E) No, a precipitate will not form.

F) A) and B)
G) B) and D)

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