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Aqueous ammonia is commercially available in a solution that is 28% (w/w) ammonia. What is the mole fraction of ammonia in such a solution?


A) 0.017
B) 0.023
C) 0.012
D) 0.24
E) 0.29

F) D) and E)
G) A) and D)

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A solution containing 0.102 g of an unknown compound dissolved in 100. mL of water has an osmotic pressure of 28.1 mmHg at 20.°C. What is the molar mass of the compound? (R = 0.08206 L • atm/K • mol, 1 atm = 760 mmHg)


A) 663 g/mol
B) 0.872 g/mol
C) 1.15 g/mol
D) 727 g/mol
E) 1.10 × 102 g/mol

F) A) and E)
G) B) and E)

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What volume of a 2.75 M solution of NaOH is required to make 500.0 mL of a 1.27 M solution of NaOH?


A) 231 mL
B) 1.72 L
C) 1.10 L
D) 440 mL
E) 909 mL

F) C) and D)
G) A) and D)

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What is the molarity of a 17.0% by mass solution of sodium acetate, NaC2H3O2 (82.0 g/mol) , in water? The density of the solution is 1.09 g/mL.


A) 0.170 M
B) 0.207 M
C) 2.07 M
D) 2.26 M
E) 1.90 M

F) A) and B)
G) A) and C)

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What is defined as the difference between the freezing point of a pure solvent and the freezing point of the solution?


A) Freezing point
B) Freezing-point elevation
C) Freezing-point depression
D) Subzero freezing
E) Supercooling

F) A) and B)
G) B) and D)

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Which solution has the highest vapor pressure?


A) 0.75 mol of a nonvolatile compound in 750 g of ethanol
B) 0.75 mol of a volatile compound in 750 g of ethanol
C) 1.5 mol of a nonvolatile compound in 750 g of ethanol
D) Solutions A and B have the same vapor pressure and it is higher than the vapor pressure of solution C.
E) Not enough information is given to determine which solution has the highest vapor pressure.

F) A) and C)
G) C) and E)

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Colligative properties are properties that depend on the number of solvent particles in solution, but not on the nature of the solvent.

A) True
B) False

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Which substance is present in the smallest proportion in a solution?


A) liquid
B) gas
C) solvent
D) solid
E) solute

F) B) and E)
G) A) and D)

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When two pure substances are mixed to form a solution


A) heat is released.
B) heat is absorbed.
C) there is an increase in entropy.
D) there is a decrease in entropy.
E) entropy is conserved.

F) C) and D)
G) B) and E)

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The structure of Vitamin B1, thiamine, is shown here. Vitamin B1 is most soluble in ________. The structure of Vitamin B1, thiamine, is shown here. Vitamin B1 is most soluble in ________.   A)  fats B)  water C)  air D)  carbon tetrachloride E)  octane


A) fats
B) water
C) air
D) carbon tetrachloride
E) octane

F) A) and E)
G) All of the above

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Which combination of a 36.0% (w/w) stock solution of acetic acid (d = 1.045 g/mL) and water will result in 1.00 kg of a 15.0% (w/w) acetic acid solution?


A) 417 mL of 36% acetic acid in 583 mL of distilled water
B) 417 g of 36% acetic acid in 583 g of distilled water
C) 360 mL of 36% acetic acid in 640 mL of distilled water
D) 360 g of 36% acetic acid in 640 g of distilled water
E) 150 g of 36% acetic acid in 850 g of distilled water

F) A) and E)
G) All of the above

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Which is most soluble in CCl4?


A) NaCl
B) H2O
C) NaOH
D) C8H18
E) CH3OH

F) A) and B)
G) B) and E)

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Calcium nitrite is used as a corrosion inhibitor in lubricants. What is the molality of a solution prepared by dissolving 18.5 g of calcium nitrite in 83.5 g of distilled water?


A) 0.181 m
B) 0.222 m
C) 0.596 m
D) 1.35 m
E) 1.68 m

F) None of the above
G) A) and B)

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Which of the following is not soluble in water?


A) Vitamin C
B) NaCl
C) CH3CH2OH
D) NH3
E) Vitamin E

F) A) and B)
G) B) and D)

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What is defined as a solution that has a higher concentration of dissolved substances than plasma?


A) Hypotonic
B) Hypertonic
C) Aplasmic
D) Plasmic
E) Colloidal

F) B) and D)
G) A) and C)

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If the shell of a raw egg is carefully dissolved away, and the egg in its flexible membrane is then placed in distilled water, the egg's volume will expand. Explain.

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The osmotic pressure of the solution ins...

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Which statement is false?


A) The vapor pressure of a solvent over a solution decreases as its mole fraction increases.
B) The solubility of a gas increases as the temperature decreases.
C) The vapor pressure of a solvent over a solution is less than that of pure solvent.
D) The greater the pressure of a gas over a solution, the greater its solubility.
E) Ionic solutes dissociate in solution, causing an enhancement of all colligative properties.

F) B) and D)
G) A) and E)

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Explain the following, on the basis of osmosis or osmotic pressure: Meat that is salted before cooking tends to dry out.

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The water passes thr...

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Which of these compounds is a strong electrolyte?


A) H2O
B) N2
C) CH3COOH (acetic acid)
D) C2H6O (ethanol)
E) KOH

F) A) and C)
G) B) and D)

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Which of these compounds is a weak electrolyte?


A) HCl
B) CH3COOH (acetic acid)
C) C6H12O6 (glucose)
D) O2
E) NaCl

F) D) and E)
G) C) and D)

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