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Why would the compound below not react with a dienophile in a Diels-Alder reaction? Why would the compound below not react with a dienophile in a Diels-Alder reaction?   A)  There are no electron withdrawing groups on the compound. B)  The compound cannot adopt thes-cis conformation. C)  The compound is not a conjugated diene. D)  There are no electron donating groups on the compound.


A) There are no electron withdrawing groups on the compound.
B) The compound cannot adopt thes-cis conformation.
C) The compound is not a conjugated diene.
D) There are no electron donating groups on the compound.

E) A) and B)
F) A) and C)

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Which of the following molecules is a naturally occurring conjugated diene?


A) Acetylene
B) None of these are correct.
C) Isoprene
D) Ethylene

E) A) and D)
F) None of the above

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C

What is the major product of the following reaction? What is the major product of the following reaction?   A)  IV B)  I C)  III D)  II


A) IV
B) I
C) III
D) II

E) B) and C)
F) None of the above

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B

Which of the following statements about the Diels-Alder reaction is true?


A) The diene can react only when it adopts thes-trans conformation.
B) The stereochemistry of the dienophile is retained in the product.
C) Electron-donating substituents in the dienophile increase the reaction rate.
D) Electron-withdrawing substituents in the diene increase reaction rate.

E) A) and B)
F) C) and D)

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What is the major product of the following reaction? What is the major product of the following reaction?   A)  II B)  IV C)  I D)  III


A) II
B) IV
C) I
D) III

E) A) and B)
F) None of the above

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Which of the following is (are) conjugated dienes? Which of the following is (are)  conjugated dienes?   A)  Only I and II B)  I, II, and III C)  Only I D)  Only II


A) Only I and II
B) I, II, and III
C) Only I
D) Only II

E) A) and B)
F) C) and D)

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D

What is the major product of the following reaction? What is the major product of the following reaction?   A)  II B)  III C)  I D)  IV


A) II
B) III
C) I
D) IV

E) B) and C)
F) A) and B)

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Which of the following isnot a feature of the Diels-Alder reaction?


A) Three ? bonds break.
B) They are initiated by peroxides.
C) They are concerted.
D) They form new six-membered rings.

E) None of the above
F) A) and D)

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What is the major product of the following reaction? What is the major product of the following reaction?   A)  II B)  III C)  I D)  IV


A) II
B) III
C) I
D) IV

E) B) and C)
F) All of the above

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