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What is the boiling point of an aqueous solution of a nonelectrolyte that has an osmotic pressure of 10.50 atm at 25°C? Kb of water is 0.52°C/m. Assume the density of the solution is the same as that of pure water.


A) 0.22°C
B) 0.429°C
C) 100.43°C
D) 99.78°C
E) 100.22°C

F) None of the above
G) A) and B)

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When 24.0 g of glucose (a nonelectrolyte) are dissolved in 500. g of water, the solution has a freezing point of -0.47°C. What is the molar mass of glucose? Kf of water is 1.86°C/m.


A) 41.9 g
B) 47.5 g
C) 54.9 g
D) 178 g
E) 190. g

F) A) and B)
G) A) and C)

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When 12.1 g of the sugar sucrose (a nonelectrolyte) are dissolved in exactly 800 g of water, the solution has a freezing point of -0.082°C. What is the molar mass of sucrose? Kf of water is 1.86°C/m.


A) 426 g
B) 99.2 g
C) 178 g
D) 266 g
E) 343 g

F) A) and C)
G) A) and B)

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What is the freezing point of an aqueous solution of a nonvolatile solute that has a boiling point of 102.5°C? For water Kf = 1.86°C/m and Kb = 0.52°C/m.


A) -8.94°C
B) -366°C
C) -0.99°C
D) 0.99°C
E) 8.94°C

F) A) and E)
G) A) and D)

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The solubility of gases in water always decreases with increasing temperature.

A) True
B) False

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A solution that contains 55.0 g of ascorbic acid (VitaminC) in 250. g of water freezes at -2.34°C. Calculate the molar mass (in units of g/mol) of the solute. Kf of water is 1.86°C/m.


A) 1.26
B) 10.9
C) 43.6
D) 175
E) 277

F) A) and B)
G) A) and C)

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A solution is prepared by adding 40.3 g of Mg(NO3)2 to 127 g of water. Calculate the mole fraction and molality of magnesium nitrate in this solution.

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mole fract...

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Maple syrup is mostly a solution of sucrose in water. Calculate the molality of the syrup if a sample freezes at -0.50°C, assuming the solute is pure sucrose. [For water, Kf is 1.86°C/m.]

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When 20.0 grams of an unknown compound are dissolved in 500. grams of benzene, the freezing point of the resulting solution is 3.77°C. The freezing point of pure benzene is 5.444°C, and the Kf for benzene is 5.12°C/m. What is the molar mass of the unknown compound?

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During osmosis


A) pure solvent diffuses through a membrane but solutes do not.
B) pure solutes diffuse through a membrane but solvent does not.
C) pure solvent and a solution both diffuse at the same time through a membrane.
D) gases diffuse through a membrane into a solution and build up pressure.

E) C) and D)
F) A) and B)

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What volume of ethanol (density = 0.7893 g/cm3) should be added to 450. mL of water in order to have a solution that freezes at -15.0°C? (For water, Kf = 1.86 °C/m.)


A) 371 mL
B) 470 mL
C) 212 mL
D) 132 mL
E) 167 mL

F) A) and C)
G) A) and D)

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Calculate the freezing point of a solution made from 22.0 g of octane (C8H18) dissolved in 148.0 g of benzene. Benzene freezes at 5.50°C and its Kf value is 5.12°C/m.


A) -1.16°C
B) 0.98°C
C) 6.66°C
D) 12.2°C
E) 5.49°C

F) B) and E)
G) A) and D)

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The solubility of gases in water usually decreases with


A) increasing pressure.
B) increasing temperature.
C) decreasing temperature.

D) All of the above
E) B) and C)

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Calculate the molality of a 15.0% by mass solution of MgCl2 in H2O. The density of this solution is 1.127 g/mL.


A) 0.157 m
B) 11.8 m
C) 1.86 m
D) 0.0134 m
E) 1.58 m

F) B) and D)
G) C) and D)

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Pure benzene, C6H6, freezes at 5.5° and boils at 80.1°C. What is the boiling point of a solution consisting of cyclohexane (C6H12) dissolved in benzene if the freezing point of this solution is 0.0°C? (For benzene, Kf = 5.12 °C/m, Kb = 2.53 °C/m; for cyclohexane, Kf = 20.0 °C/m, Kb = 2.79°C/m)


A) 82.8°C
B) 91.2°C
C) 80.9°C
D) 77.4°C
E) 83.1°C

F) A) and E)
G) A) and D)

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Explain the following, on the basis of osmosis or osmotic pressure: Drinking salt water actually dehydrates our tissues.

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The water passes fro...

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What is the molar mass of toluene if 0.85 g of toluene depresses the freezing point of 100. g of benzene by 0.47°C? Kf of benzene is 5.12°C/m.


A) 92.6 g/mol
B) 78.0 g/mol
C) 10.7 g/mol
D) 81.8 g/mol
E) 927 g/mol

F) B) and D)
G) A) and E)

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In which of the following solvents would you expect KBr to be most soluble?


A) C6H14 (hexane)
B) CH3CH2OH (ethanol)
C) C6H6 (benzene)
D) CCl4 (carbon tetrachloride)
E) C6H12 (cyclohexane)

F) C) and D)
G) A) and C)

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What is the concentration of O2(g)in water at 25°C exposed to a partial pressure of oxygen of 325 mmHg? The Henry's law constant for oxygen gas at 25°C is 1.3 * 10-3 mol/L·atm.

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5.6 * 10

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What is the osmotic pressure of a solution that contains 13.7 g of propyl alcohol (C3H7OH) dissolved in enough water to make 500. mL of solution at 27°C?


A) 0.014 atm
B) 0.037 atm
C) 0.456 atm
D) 0.01 atm
E) 11.2 atm

F) A) and B)
G) A) and E)

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