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The combustion of butane produces heat according to the equation 2C4H10(g) + 13O2(g) \rarr 8CO2(g) + 10H2O(l) Δ\Deltarxn = -5,314 kJ/mol What is the heat of combustion per gram of butane?


A) -32.5 kJ/g
B) -45.7 kJ/g
C) -91.5 kJ/g
D) -2,656 kJ/g
E) -15,440 kJ/g

F) D) and E)
G) C) and D)

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Potential energy is


A) the energy stored within the structural units of chemical substances.
B) the energy associated with the random motion of atoms and molecules.
C) solar energy, i.e.energy that comes from the sun.
D) energy available by virtue of an object's position.

E) A) and D)
F) All of the above

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A home aquarium is an example of an open system.

A) True
B) False

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If 2Mg(s)+ O2(g) \rarr 2MgO(s), Δ\Delta H° = -1203.6 kJ/mol. For Mg(s)+ (1/2)O2(g) \rarr MgO(s), the enthalpy change is Δ\Delta H = -601.8 kJ/mol.

A) True
B) False

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A feverish student weighing 75 kilograms was immersed in 400.kg of water at 4.0°C to try to reduce the fever.The student's body temperature dropped from 40.0°C to 37.0°C.Assuming the specific heat of the student to be 3.77 J/g·°C, what was the final temperature of the water?

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The heat of combustion of propane, C3H8, 2220 kJ/mol.The specific heat of copper is 0.385 J/g.°C.How many grams of propane must be burned to raise the temperature of a 10.0 kg block of copper from 25.0°C to 65.0°C, assuming none of the heat is lost to the surroundings

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The combustion of one mole of benzene, C6H6, in oxygen liberates 3268 kJ of heat.The products of the reaction are carbon dioxide and water. How much heat is given off when 183 g of oxygen are reacted with excess benzene?

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Given the thermochemical equation 2SO2 + O2 \rarr 2SO3, Δ\Deltarxn = -198 kJ/mol, what is the standard enthalpy change for the decomposition of one mole of SO3?


A) 198 kJ/mol
B) -99 kJ/mol
C) 99 kJ/mol
D) 396 kJ/mol
E) -198 kJ/mol

F) A) and B)
G) A) and C)

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C. The heat capacity of the calorimeter is 2.21 kJ/°C.The heat capacity of water = 4.184 J/g·°C. What is the heat of combustion, in megajoules (MJ), per mole of pentane?

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When 0.7521 g of benzoic acid was burned in a calorimeter containing 1,000.g of water, a temperature rise of 3.60°C was observed. What is the heat capacity of the bomb calorimeter, excluding the water? The heat of combustion of benzoic acid is -26.42 kJ/g.


A) 15.87 kJ/°C
B) 4.18 kJ/°C
C) 5.52 kJ/°C
D) 1.34 kJ/°C
E) 752.1 kJ/°C

F) B) and D)
G) A) and B)

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The combustion of butane produces heat according to the equation 2C4H10(g) + 13O2(g) \rarr 8CO2(g) + 10H2O(l) Δ\Deltarxn= -5,314 kJ/mol How many grams of CO2 are produced per 1.00 *104 kJ of heat released?


A) 23.4 g
B) 44.0 g
C) 82.3 g
D) 187 g
E) 662 g

F) B) and E)
G) A) and B)

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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25°C.Assume the volume of liquid H2O is negligible compared to that of vapor. (1 L·atm = 101.3 J)


A) 6,190 kJ
B) 6.19 kJ
C) 61.1 J
D) 5.66 kJ
E) 518 J

F) C) and D)
G) B) and D)

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Given 2Al(s) + (3/2) O2(g) \rarr Al2O3(s) , Δ\Deltaf = -1,670 kJ/mol for Al2O3 (s) . Determine Δ\Delta H° for the reaction 2Al2O3(s) \rarr 4Al(s) + 3O2(g) .


A) 3,340 kJ/mol
B) 1,670 kJ/mol
C) -3,340 kJ/mol
D) -1,670 kJ/mol
E) -835 kJ/mol

F) A) and B)
G) B) and D)

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Naphthalene combustion can be used to calibrate the heat capacity of a bomb calorimeter.The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was burned in a calorimeter containing 1,000.g of water, a temperature rise of 4.21°C was observed. What is the heat capacity of the bomb calorimeter excluding the water?


A) 32.9 kJ/°C
B) 7.8 kJ/°C
C) 3.64 kJ/°C
D) 1.76 kJ/°C
E) 15.3 kJ/°C

F) None of the above
G) C) and D)

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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol. If 135 mL of 0.450 M HI at 23.15°C is mixed with 145 mL of 0.500 M NaOH, also at 23.15°C, what will the maximum temperature reached by the resulting solution? (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g·°C, and that the density of the final solution is that of water.)


A) 26.06°C
B) 29.19°C
C) 32.35°C
D) 20.24°C
E) 36.57°C

F) B) and D)
G) None of the above

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Given that CaO(s) + H2O(l) \rarr Ca(OH) 2(s) , Δ\Deltarxn = -64.8 kJ/mol, how many grams of CaO must react in order to liberate 525 kJ of heat?


A) 6.92 g
B) 56.1 g
C) 455 g
D) 606 g
E) 3.40 * 104 g

F) D) and E)
G) A) and C)

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The heat of solution of ammonium nitrate is 26.2 kJ/mol. If a 5.368 g sample of NH4NO3 is added to 40.0 mL of water in a calorimeter at 23.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 650.J/°C.)


A) 14.3°C
B) 20.8°C
C) -7.7°C
D) 25.6°C
E) 21.4°C

F) B) and E)
G) D) and E)

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Find Δ\Deltarxn for the reaction 2Ag2S(s)+ 2H2O(l) \rarr 4Ag(s)+ 2H2S(g)+ O2(g). [ Δ\Deltaf (Ag2S(s))= -32.6 kJ/mol; Δ\Deltaf (H2S(g))= -20.5 kJ/mol; Δ\Deltaf (H2O(l))= -285.5 kJ/mol]

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The heat of solution of KCl is 17.2 kJ/mol and the lattice energy of KCl(s) is 701.2 kJ/mol.Calculate the total heat of hydration of 1 mol of gas phase K+ ions and Cl- ions.


A) 718 kJ
B) 684 kJ
C) -684 kJ
D) -718 kJ
E) None of these.

F) C) and E)
G) All of the above

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The specific heat of silver is 0.235 J/g·°C. How many joules of heat are required to heat a 75 g silver spoon from 20°C to 35°C?

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