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The volume of 0.25 mol of a gas at 72.7 kPa and 15°C is __________ m3.


A) 8.1 × 10-5
B) 1.2 × 10-4
C) 4.3 × 10-4
D) 8.2 × 10-3
E) 2.2 × 10-1

F) A) and D)
G) A) and E)

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The reaction of 100 mL of Cl2 gas with 100 mL of CH4 gas via the equation: Cl2 (g) + CH4 (g) → HCl (g) + CH3Cl (g) Will produce a total of __________ mL of products if pressure and temperature are kept constant.


A) 100
B) 50
C) 200
D) 150
E) 250

F) All of the above
G) D) and E)

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The Mond process produces pure nickel metal via the thermal decomposition of nickel tetracarbonyl: Ni(CO) 4 (l) → Ni (s) + 4CO (g) . What volume (L) of CO is formed from the complete decomposition of 444 g of Ni(CO) 4 at 752 torr and 22.0°C?


A) 0.356
B) 63.7
C) 255
D) 20.2
E) 11.0

F) B) and D)
G) A) and E)

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Which of the following is not part of the kinetic-molecular theory?


A) Atoms are neither created nor destroyed by ordinary chemical reactions.
B) Attractive and repulsive forces between gas molecules are negligible.
C) Gases consist of molecules in continuous, random motion.
D) Collisions between gas molecules do not result in the loss of energy.
E) The volume occupied by all of the gas molecules in a container is negligible compared to the volume of the container.

F) B) and C)
G) B) and D)

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The density of chlorine gas at 1.21 atm and 34.9°C is __________ g/L.


A) 0.0479
B) 0.295
C) 0.423
D) 1.70
E) 3.39

F) D) and E)
G) A) and B)

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The volume of hydrogen gas at 38.0°C and 763 torr that can be produced by the reaction of 4.33 g of zinc with excess sulfuric acid is __________ L.


A) 1.68
B) 2.71 × 10-4
C) 3.69 × 104
D) 2.84
E) 0.592

F) A) and B)
G) C) and E)

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A sample of a gas originally at 25°C and 1.00 atm pressure in a 2.5 L container is subject to a pressure of 0.85 atm and a temperature of 15°C. The final volume of the gas is __________ L.


A) 3.0
B) 2.8
C) 2.6
D) 2.1
E) 0.38

F) D) and E)
G) All of the above

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Sodium bicarbonate is reacted with concentrated hydrochloric acid at 25.0°C and 1.50 atm. The reaction of 7.75 kg of bicarbonate with excess hydrochloric acid under these conditions will produce __________ L of CO2.


A) 1.82 x 103
B) 2.85 x 104
C) 1.82 x 104
D) 1.50 x 103
E) 8.70 x 102

F) A) and E)
G) A) and D)

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SO2 (5.00 g) and CO2 (5.00 g) are placed in a 750.0 mL container at 50.0°C. The partial pressure of SO2 in the container was __________ atm.


A) 2.76
B) 4.02
C) 6.78
D) 0.192
E) 1.60

F) A) and E)
G) B) and D)

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The density of air at STP is 1.285 g/L. Which of the following cannot be used to fill a balloon that will float in air at STP?


A) CH4
B) NO
C) Ne
D) N H3
E) HF

F) B) and E)
G) A) and B)

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A sample of H2 gas (12.28 g) occupies 100.0 L at 400.0 K and 2.00 atm. A sample weighing 9.49 g occupies __________ L at 353 K and 2.00 atm.


A) 109
B) 68.2
C) 54.7
D) 147
E) 77.3

F) C) and E)
G) D) and E)

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The density of N2O at 1.53 atm and 45.2°C is __________ g/L.


A) 18.2
B) 1.76
C) 0.388
D) 9.99
E) 2.58

F) C) and D)
G) B) and E)

Correct Answer

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At 333 K, which of the pairs of gases below would have the most nearly identical rates of effusion?


A) N2O and NO2
B) CO and N2
C) N2 and O2
D) CO and CO2
E) NO2 and N2O4

F) A) and D)
G) A) and B)

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A gas is considered "ideal" if one mole of it in a one-liter container exerts a pressure of exactly 1 atm at room temperature.

A) True
B) False

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SO2 (5.00 g) and CO2 (5.00 g) were placed in a 750.0 mL container at 50.0°C. The partial pressure of CO2 in the container was __________ atm.


A) 6.78
B) 2.76
C) 1.60
D) 0.192
E) 4.02

F) A) and E)
G) B) and D)

Correct Answer

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In ideal gas equation calculations, expressing pressure in Pascals (Pa) , necessitates the use of the gas constant, R, equal to __________.


A) 0.08206 atm L mol-1K-1
B) 8.314 J mol-1K-1
C) 62.36 L torr mol-1K-1
D) 1.987 cal mol-1K-1
E) none of the above

F) B) and E)
G) A) and D)

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The pressure in a 12.2 L vessel that contains 2.34 g of carbon dioxide, 1.73 g of sulfur dioxide, and 3.33 g of argon, all at 42 °C is __________ mm Hg.


A) 263
B) 134
C) 395
D) 116
E) 0.347

F) D) and E)
G) All of the above

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The density of nitric oxide (NO) gas at 1.21 atm and 46.2°C is __________ g/L.


A) 0.0462
B) 0.722
C) 1.39
D) 0.319
E) 9.6

F) D) and E)
G) All of the above

Correct Answer

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A 1.44-g sample of an unknown pure gas occupies a volume of 0.335 L at a pressure of 1.00 atm and a temperature of 100.0°C. The unknown gas is __________.


A) argon
B) helium
C) krypton
D) neon
E) xenon

F) D) and E)
G) A) and B)

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The volume of HCl gas required to react with excess Ca to produce 11.4 L of hydrogen gas at 1.62 atm and 62.0°C is __________ L.

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