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A 0.100 m K2SO4 solution has a freezing point of -0.43°C. What is the van't Hoff factor for this solution? Kf = 1.86°C/m


A) 0.77
B) 1.0
C) 2.3
D) 3.0
E) >3.0

F) A) and E)
G) A) and B)

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If the shell of a raw egg is carefully dissolved away, and the egg in its flexible membrane is then placed in distilled water, the egg's volume will expand. Explain.

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Benzaldehyde ( Benzaldehyde (   = 106.1 g/mol) , also known as oil of almonds, is used in the manufacture of dyes and perfumes and in flavorings. What would be the freezing point of a solution prepared by dissolving 75.00 g of benzaldehyde in 850.0 g of ethanol? K<sub>f</sub> = 1.99°C/m, freezing point of pure ethanol = -117.3°C. A)  -117.5°C B)  -118.7°C C)  -119.0°C D)  -120.6°C E)  < -121°C = 106.1 g/mol) , also known as oil of almonds, is used in the manufacture of dyes and perfumes and in flavorings. What would be the freezing point of a solution prepared by dissolving 75.00 g of benzaldehyde in 850.0 g of ethanol? Kf = 1.99°C/m, freezing point of pure ethanol = -117.3°C.


A) -117.5°C
B) -118.7°C
C) -119.0°C
D) -120.6°C
E) < -121°C

F) None of the above
G) B) and E)

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What is the mole fraction of Ar in a mixture containing 10.1 g of Ne, 79.9 g of Ar, and 83.8 g of Kr?


A) 0.40
B) 0.25
C) 0.20
D) 0.14
E) 0.058

F) B) and D)
G) A) and B)

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A saturated solution of carbon dioxide in water contains 3.00 g of CO2 when the CO2 partial pressure is 8.0 atm. What mass of CO2 will escape if the partial pressure is lowered to 3.2 atm?


A) 0.90 g
B) 1.20 g
C) 1.40 g
D) 1.80 g
E) 2.20 g

F) None of the above
G) A) and D)

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The Tyndall effect


A) is observed in concentrated solutions.
B) is observed only in dilute solutions.
C) is observed in colloidal dispersions.
D) is caused by Brownian motion.
E) is used to determine the osmotic pressure of solutions.

F) D) and E)
G) B) and C)

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The vapor pressure of pure acetone (propanone) is 266 torr. When a non-volatile solute is added, the vapor pressure of acetone above the solution falls to 232 torr. What is the mole fraction of the non-volatile solute in the solution?


A) 0.87
B) 0.69
C) 0.32
D) 0.13
E) 0.045

F) C) and D)
G) D) and E)

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How many moles of solute particles are present in 100.0 mL of 2.50 M (NH4) 3PO4?


A) 0.100 mol
B) 0.250 mol
C) 0.500 mol
D) 0.750 mol
E) l.00 mol

F) A) and E)
G) A) and D)

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If a solute dissolves in an endothermic process


A) H bonds must exist between solvent and solute.
B) strong ion-dipole forces must exist in the solution.
C) the solute must be a gas.
D) the entropy of the solution is immaterial.
E) the entropy of the solution must be greater than that of its pure components.

F) C) and D)
G) A) and B)

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A 2.0% (w/v) solution of sodium hydrogen citrate, Na2C6H6O7, which also contains 2.5% (w/v) of dextrose, C6H12O6, is used as an anticoagulant for blood which is to be used for transfusions. What is the molarity of the sodium hydrogen citrate in the solution?


A) 0.085 M
B) 0.19 M
C) 0.53 M
D) 1.2 M
E) 1.3 M

F) C) and E)
G) A) and E)

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The solubility of the oxidizing agent potassium permanganate is 7.1 g per 100.0 g of water at 25°C. What is the mole fraction of potassium permanganate in this solution?


A) 0.0080
B) 0.0086
C) 0.066
D) 0.45
E) 0.48

F) C) and D)
G) B) and E)

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List five important intermolecular forces that operate in globular proteins, and explain what parts of the molecule are involved in these forces.

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1. Ion-dipole forces. These exist betwee...

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Colligative properties depend on


A) the chemical properties of the solute.
B) the chemical properties of the solvent.
C) the masses of the individual ions.
D) the molar mass of the solute.
E) the number of particles dissolved.

F) A) and D)
G) All of the above

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Which of the following aqueous solutions should demonstrate the most ideal behavior?


A) 0.1 M K2SO4
B) 0.1 M CaCl2
C) 3.0 M LiF
D) 0.1 M MgSO4
E) 0.1 M NaCl

F) D) and E)
G) A) and C)

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Hexachlorophene is used as a disinfectant in germicidal soaps. What mass of hexachlorophene ( Hexachlorophene is used as a disinfectant in germicidal soaps. What mass of hexachlorophene (   = 406.9 g/mol)  must be added to 125 g of chloroform to give a solution with a boiling point of 62.60°C? K<sub>b</sub> = 3.63°C/m, boiling point of pure chloroform = 61.70°C A)  12.6 g B)  17.2 g C)  31.0 g D)  34.4 g E)  101 g = 406.9 g/mol) must be added to 125 g of chloroform to give a solution with a boiling point of 62.60°C? Kb = 3.63°C/m, boiling point of pure chloroform = 61.70°C


A) 12.6 g
B) 17.2 g
C) 31.0 g
D) 34.4 g
E) 101 g

F) B) and C)
G) C) and E)

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The heat of solution is the total enthalpy change when a solution is formed from the separated solute and solvent.

A) True
B) False

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Calculate the molarity of a solution prepared by diluting 1.85 L of 6.5 M KOH to 11.0 L.


A) 0.28 M
B) 0.91 M
C) 1.1 M
D) 3.1 M
E) 3.9 M

F) A) and B)
G) A) and C)

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Determine the freezing point of a solution which contains 0.31 mol of sucrose in 175 g of water. Kf = 1.86°C/m


A) 3.3°C
B) 1.1°C
C) 0.0°C
D) -1.1°C
E) -3.3°C

F) A) and B)
G) A) and C)

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The chemist, Anna Lytic, must prepare 1.00 kg of 15.0% (w/w) acetic acid using a stock solution which is 36.0% (w/w) acetic acid (d = 1.045 g/mL) . Which of the following combinations will give her the solution she wants?


A) 417 mL of 36% acetic acid in 583 mL of distilled water
B) 417 g of 36% acetic acid in 583 g of distilled water
C) 360 mL of 36% acetic acid in 640 mL of distilled water
D) 360 g of 36% acetic acid in 640 g of distilled water
E) 150 g of 36% acetic acid in 850 g of distilled water

F) A) and D)
G) C) and E)

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When two pure substances are mixed to form a solution


A) heat is released.
B) heat is absorbed.
C) there is an increase in entropy.
D) there is a decrease in entropy.
E) entropy is conserved.

F) All of the above
G) C) and D)

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